Bis[4-(dimethyl­amino)­pyridinium] bis­[4-(dimethyl­amino)­pyridine-κN 1]tetra­kis­(thio­cyanato-κN)manganate(II)

نویسندگان

  • Susanne Wöhlert
  • Inke Jess
  • Christian Näther
چکیده

In the crystal structure of the title compound, (C7H11N2)2[Mn(NCS)4(C7H10N2)2], the manganese(II) cations are coordinated by four N-bonded thio-cyanate anions and two N-bonded 4-(dimethyl-amino)-pyridine ligands into discrete complex dianions. For charge balance, two 4-(dimethylamino)pyridine counter cations are present, which do not coordinate to the metal cation. The asymmetric unit consists of one manganese(II) cation, four thio-cyanate anions and two 4-(dimethyl-amino)-pyridine ligands, as well as two protonated 4-(dimethyl-amino)-pyridinium cations. The discrete complex anions are connected to the non-coordinating pyridinium cations by weak N-H⋯S hydrogen-bonding inter-actions.

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Crystal structures of bis­[4-(di­methyl­amino)­pyridinium] tetra­kis­(thio­cyanato-κN)manganate(II) and tris­[4-(di­methyl­amino)­pyridinium] penta­kis(thio­cyanato-κN)manganate(II)

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012